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Synthesis and structural characterization of arsinoamide and its metal complexes
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The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).
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Synthesis and structural characterization of arsinoamide and its metal complexes, Xiao Chen
- Jazyk
- Rok vydání
- 2019
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Platební metody
2021 2022 2023
Navrhnout úpravu
- Titul
- Synthesis and structural characterization of arsinoamide and its metal complexes
- Jazyk
- anglicky
- Autoři
- Xiao Chen
- Vydavatel
- Cuvillier Verlag
- Rok vydání
- 2019
- ISBN10
- 373697034X
- ISBN13
- 9783736970342
- Kategorie
- Skripta a vysokoškolské učebnice
- Anotace
- The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).